From his official results pages (bold – final, red – lost since his first Grand Slam):

Year

Australian

French

Wimbledon

US
1999

Rafter

Novak

1st

1st

2000

Clement

Corretja

Kafelnikov

Ferrero
3rd

4th

1st

3rd
2001

Clement

Corretja

Henman

Agassi
3rd

QF

QF (beat Sampras in 4th)

4th
2002

Haas

Arazi

Ancic

Mirnyi
4th

1st

1st

4th
2003

Nalbandian

Horna

Philippoussis

Nalbandian
4th

1st

3:0 (7-6, 6-2, 7-6)

4th
2004

Safin

Kuerten

Roddick

Hewitt
3:0 (7-6, 6-4, 6-2)

3rd

3:1 (4-6, 7-5, 7-6, 6-4)

3:0 (6-0, 7-6, 6-0)
2005

Safin

Nadal

Roddick

Agassi
SF 2:3 (7-5, 4-6, 7-5, 6-7, 7-9)

SF 1:3 (3-6, 6-4, 4-6, 3-6)

3:0 (6-2, 7-6, 6-4)

3:1 (6-3, 2-6, 7-6, 6-1)
2006

Baghdatis

Nadal

Nadal

Roddick
3:1 (5-7, 7-5, 6-0, 6-2)

1:3 (1-6, 6-1, 6-4, 7-6)

3:1 (6-0, 7-6, 6-7, 6-3)

3:1 (6-2, 4-6, 7-5, 6-1)
2007

Gonzalez

Nadal

Nadal

Djokovich
3:0 (7-6, 6-4, 6-4)

1:3 (6-3, 4-6, 6-3, 6-4)

3:2 (7-6, 4-6, 7-6, 2-6, 6-2)

3:0 (7-6, 7-6, 6-4)
2008

Djokovic

Nadal

Nadal

Murray
SF 0:3 (5-7, 3-6, 6-7)

0:3 (6-1, 6-3, 6-0)

2:3 (6-4, 6-4, 6-7, 6-7, 7-9)

3:0 (6-2, 7-5, 6-2)
2009

Nadal

Söderling

Roddick

del Potro
2:3 (7-5, 3-6, 7-6, 3-6, 6-2)

3:0 (6-1, 7-6, 6-4)

3:2 (4-6, 7-6, 7-6, 3-6, 16-14)

2:3 (6-3, 6-7, 6-4, 6-7, 2-6)
2010

Murray

Söderling

Berdych

Djokovic
3:0 (6-3, 6-4, 7-6)

QF 1:3 (6-3, 3-6, 5-7, 4-6)

QF 1:3 (4-6, 6-3, 1-6, 4-6)

SF 2:3 (7-5, 1-6, 7-5, 2-6, 5-7)
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